CORONA CORD TIRE CO. V. DONOVAN CHEM. CORP., 276 U. S. 358 (1928)Subscribe to Cases that cite 276 U. S. 358
U.S. Supreme Court
Corona Cord Tire Co. v. Donovan Chem. Corp., 276 U.S. 358 (1928)
Corona Cord Tire Company v. Donovan Chemical Corporation
Argued January 16, 17, 1928
Decided April 9, 1928
276 U.S. 358
CERTIORARI TO THE CIRCUIT COURT OF APPEALS
FOR THE THIRD CIRCUIT
1. Discovery that a change of ingredients in a process speeds the result entitles the inventor to any other advantages flowing from the substitution. P. 276 U. S. 369.
2. The fact that a party was the first to discover and obtain a valid patent for a process of producing a substance held irrelevant to the question whether he was the first discoverer of its utility as an ingredient in another process. P. 276 U. S. 370.
3. Under Rev.Stats. § 4886, a person is not to be denied a patent because of a publication printed after his discovery and not more than two years before his application. P. 276 U. S. 372.
4. Invention of a process for vulcanizing rubber, and its reduction to practice, may be established by proof of actual tests in which test chanroblesvirtualawlibrary
5. Reckless overstatements of the extent of earlier reduction to practice by the applicant, made in affidavits filed in a patent proceeding to meet a reference of prior publication, held not destructive of the presumption of validity accompanying the patent where the sufficiency of the affidavits in other respects rendered such statements superfluous. P. 276 U. S. 374.
6. Where a patentee met a reference in the patent proceeding merely by evidence of his own priority of discovery, his failure then to attack its sufficiency in other respects did not subject him to the burden of proving it insufficient in a suit to enjoin infringement of the patent. P. 276 U. S. 374.
7. The findings of a trial court which heard the witnesses are not conclusive here when contrary to the findings of the circuit court of appeals made in the same case, and of the trial court in another case, upon the same evidence. P. 276 U. S. 375.
8. Priority of discovery may be proved by one witness, not financially interested, in connection with other circumstances. P. 276 U. S. 382.
9. One who first discovered and proved the utility of an improvement in a process cannot be said to have abandoned his invention, as against a subsequent discoverer or patentee, because he did not use the discovery commercially or apply for a patent. P. 276 U. S. 384.
10. A claim to the exclusive use of a large group of related chemical compounds, unsupported by proof that all have a common quality rendering each useful in the process patented, is too broad. P. 276 U. S. 385.
11. Patent No. 1,411,231, issued March 28, 1922, to Weiss for a process of vulcanizing rubber by combining with the rubber compound, diphenylguanidine, or "a disubstituted guanidine," and for the vulcanized product, held invalid. P. 276 U. S. 385.
16 F.2d 419 reversed.
Certiorari, 273 U.S. 692, to a decree of the circuit court of appeals which reversed a decree of the district court, 10 F.2d 298, dismissing a bill to enjoin infringement of a patent. See also Dovan Chemical Corp'n v. Nat'l Aniline Co., 292 F.5d 5. chanroblesvirtualawlibrary
MR. CHIEF JUSTICE TAFT delivered the opinion of the Court.
This is a bill by the Dovan Chemical Corporation against the Corona Cord Tire Company to enjoin infringement of a patent issued to Morris L. Weiss, assignor of the Dovan Chemical Corporation. The district court chanroblesvirtualawlibrary
for the Western District of Pennsylvania dismissed the bill for lack of validity of the patent. 10 F.2d 598. The dismissal was reversed, and the patent and the infringement charged were both sustained by the Circuit Court of Appeals for the Third Circuit. 16 F.2d 419. A writ of certiorari was granted, 273 U.S. 692, because in the prior case of Dovan Chemical Corp. v. National Aniline & Chemical Company, 292 F.5d 5, the Second Circuit Court of Appeals had reversed the decree of the District Court for the Southern District of New York (not reported) in favor of the Dovan Corporation, and had held that the patent was invalid on the ground that Weiss was not the first discoverer.
The patent in suit relates to the vulcanization of rubber. Vulcanizing consists in mixing a small amount of sulphur with rubber and subjecting the mixture to heat for a period of time, during which a chemical combination of the rubber and sulphur takes place and commercial rubber is made. The patentee recites that the object of his invention is to
"improve rubber compounds so that the finished product shall be of superior quality and so that the time required for vulcanization shall be greatly reduced over that ordinarily required for such a purpose. It is known that, when certain organic substances are added to the rubber mix during the compounding, a catalytic or similar action is produced which causes the rubber or similar gum to unite or react more rapidly and thoroughly with sulphur or other vulcanizing agents."
The patentee continues: "I have discovered that disubstituted guanidines, particularly diphenylguanidine, is particularly effective for this purpose." (This substance is indicated by the formula given in the patent.)
He says further:
"I am aware that triphenylguanidine has been suggested, and probably used to some extent, as an accelerator
in the vulcanization of rubber, but the use of diphenylguanidine for that purpose appears to have been unknown prior to my researches on this substance."
"I have found that diphenylguanidine is much more powerful and efficacious as an accelerator in vulcanization than triphenylguanidine. For example, in the vulcanization of hard rubber articles, the use of diphenylguanidine not only hastens the vulcanizing action, but results in a final product much superior in texture, strength, durability, and aging qualities over that when the triphenylguanidine is used."
The patentee makes a short reference to a formula by which he produces the rubber mix, in which he says:
"The rubber may be compounded in the following proportions: 50 parts by weight of new rubber, 45.5 parts by weight of zinc oxide, 3.5 parts by weight of sulphur, 1 part by weight of diphenylguanidine. These are mixed together in any suitable way, such as by milling, and then vulcanized or cured in the usual molds or otherwise under heat corresponding to a steam pressure of about 40 lbs. per square inch. This vulcanizing temperature should be continued until the compound is suitably vulcanized, which requires from 10 to 20 minutes, depending upon the shape and size of the articles being vulcanized."
The patent contains twelve claims. Those mainly relied on are: the fourth, for "the process of treating rubber or similar materials which comprises combining with the rubber compound diphenylguanidine;" the eighth, for "the process of treating rubber or similar materials, which comprises combining with the rubber compound a vulcanizing agent and diphenylguanidine;" and the twelfth, for "a vulcanized compound of rubber or similar material combined with a vulcanizing agent and diphenylguanidine."
Vulcanizing is old and well known. Its present high state of development represents an evolution of about 80 chanroblesvirtualawlibrary
years. Practically all rubber must be vulcanized for commercial use. The amount of sulphur in the mixture is comparatively small, as, for instance, 4 to 10 parts of sulphur to 100 parts of rubber. The remainder of the mixture may be all rubber or it may be partly rubber and partly other ingredients such as fillers and pigments, the other ingredient used most widely being zinc oxide. In the manufacture of automobile tires, a considerable proportion of zinc oxide is generally used. A very old and well known proportion has been 50 parts of rubber, 45 parts of zinc oxide and 5 parts of sulphur, and is the one shown in the specification of the patent. The mixture is "cured" by subjecting it to heat to make the vulcanized rubber of commerce. Platen molds have to be provided for giving the desired form to the rubber vulcanized. Steam has to be supplied for heating the molds and the rubber mix during the "cure." A "cure" is the successful completion of the chemical union or vulcanization of the rubber with the sulphur. The fact of a successful "cure" for practical purposes is established by a simple and short method called the thumb and tooth test. By this test, rubber chemists settle the fact and determine by the resulting product the satisfactory quality of the stock or the mix for vulcanization, and they become expert at it. If by this test the product is not well united chemically, it is said to be "undercured" or "overcured," and then the operator changes the ingredients or the time of the process. When it is important to determine with greater exactness the tensile strength and degree of elasticity or other qualities of the product, a special machine measure or test is used, but the thumb and tooth test is the frequent way of knowing a cure, and it is a satisfactory one for everyday use in business.
It has been known that a "cure" can be hastened by mixing with the ingredients a small quantity of what chanroblesvirtualawlibrary
is called an accelerator or vitalizer. Inorganic substances like lime or litharge were originally employed as such, but it was subsequently found that certain organic substances were more powerful, or more "active," as the term is, and they came into more general use. The heat to which the rubber mixed with sulphur is subjected has a deleterious effect upon the substance of the raw rubber, and the longer the heating, the greater the injury. An accelerator, as it lessens the time of the cure, not only increases the output of the equipment used but reduces the danger of deterioration of the product. An accelerator thus improves the elasticity, tensile strength, and other desirable commercial qualities of the finished product. It is not fully understood what the vitalizing or catalytic action of the accelerator is, but its existence and its results have long been known.
The patentee, in his specifications, speaks of triphenylguanidine, and compares its operation as an accelerator with that guanidine, the utility of which as an accelerator he claims to have discovered, called diphenylguanidine. Guanidines are a group of organic substances which have become prominent and important in this quest for useful accelerators. The monophenylguanidine and the diphenylguanidine and the triphenylguanidine are closely related chemically. Their long names, used to indicate the variation in the component elements, have been shortened so that it is usual to refer to diphenylguanidine by letters as "D.P.G." and the triphenylguanidine as "T.P.G."
So closely do the chemical compositions of these two resemble each other that the petitioner contends that the patent is invalid because the utility of D.P.G. as an accelerator was plainly indicated by general chemical knowledge, and did not involve patentable discovery after T.P.G. had proven to be a good one for this purpose. But we cannot agree with this view. The catalytic action chanroblesvirtualawlibrary
of an accelerator cannot be forecast by its chemical composition, for such action is not understood, and is not known except by actual test.
The respondent attempts to show that the resulting improvement in the rubber product by the use of diphenylguanidine was something different from that in the use of other accelerators. The good results of the use of diphenylguanidine are chiefly or wholly due to its greater activity and the lessened time of the cure. The expert evidence seems to show that T.P.G. as an accelerator develops the same desirable qualities, set forth on behalf of respondent, in the vulcanized rubber as does D.P.G., except that the cure of the latter is more rapid with its to be expected advantages. Moreover, claims of peculiar usefulness of D.P.G. in other than its "activity" and speed as an accelerator, even if proven, could not in any degree affect the issue in this case. If employment of D.P.G. as a useful accelerator was a discovery by Weiss, prior to any one else, Weiss, or his assignee, is entitled to all the advantages that flow from that increased activity or from any other quality in its use as such. Roberts v. Ryer, 91 U. S. 150, 91 U. S. 157; Stow v. Chicago, 104 U. S. 547, 104 U. S. 550; Lovell Mfg. Co. v. Cary, 147 U. S. 623, 147 U. S. 634.
It does not, on the other hand, give Weiss any more right to appropriate D.P.G. as an accelerator because he may have elaborated in his specifications other advantages from its use than if he had not mentioned them. Nor, on the other hand, does it minimize or affect the priority of completed discovery by some one else before Weiss that the prior discoverer may not have perceived and stated all the advantages of an earlier use of D.P.G. as an accelerator.
Judge Hough, of the Second Circuit, truly said, therefore, that this patent meant, condensed in one sentence: "I claim the use of D.P.G. as an accelerator, because I chanroblesvirtualawlibrary
was the first person who observed its efficacy for that purpose."
Similarly, the examiner in the Patent Office who allowed the patent said that Weiss' application was "no more than a broad disclosure of the use of [D.P.G.] without disclosing any details other than those usually employed with accelerators of this class."
The patent in suit was applied for November 12, 1921, and was granted March 28, 1922. Weiss had referred in the specifications of this patent to another patent of his which was applied for July 2, 1921, and granted July 11, 1922. This latter patent was for a process for making D.P.G. in large or commercial quantities. In the application for that patent, the patentee pointed out that, before his process was discovered, D.P.G. could not be made except in small quantities for chemical research because the cost was prohibitive. The validity of the Weiss patent for a process in making diphenylguanidine is not attacked. The new patented process, by reason of the lessened cost ,has resulted in the very great use of D.P.G. for commercial purposes, and has been very profitable. But the purpose of securing the patent in suit and maintaining its validity is more ambitious. It is not to protect and preserve the new process already being safely enjoyed, but it is to prevent the use of D.P.G. as an accelerator, however made by any process that may be subsequently discovered. It is to enlarge a monopoly of D.P.G. as an accelerator, and is thus in effect to discourage effort to find other and cheaper means of making it. What we have to decide here is not the priority of discovery of the cheap process of making the accelerator D.P.G., which it is conceded Weiss invented, but whether he was the first person to discover the efficacy of D.P.G. as an accelerator. whether made by any process, cheap or costly. chanroblesvirtualawlibrary
We feel it necessary to call attention to a lack of relevancy of Weiss' successful process patent in the case before us because the majority opinion in the circuit court of appeals seems to us erroneously to have confused the credit due to Weiss for the process patent, already conceded, with his right to his present claim of entire monopoly of the use of D.P.G. as an accelerator.
The issues and the evidence in this case cannot be considered and discussed without reference to a paper read by Dr. George Kratz, a rubber chemist at the Philadelphia meeting of the American Chemical Society between the 2d and the 6th of September, 1919. It was entitled "The Action of Certain organic Accelerators in the Vulcanization of Rubber," and was a review of the comparative excellence of a number of well known and used accelerators, as well as that of D.P.G. with T.P.G., in which he found D.P.G. to be very much more active than T.P.G. Then, under an experimental part, he described the kinds of rubber used, the proportions of rubber and sulphur in the mixture, and the manner in which the accelerator was incorporated and the method of vulcanization. He said:
"The rubber used was good quality, first latex, pale crepe, and the same lot was employed in all mixtures. All mixtures were made under standard conditions; the average time of each batch on the mill was 17.5 min. The same proportion of rubber and sulphur -- 92.5 parts rubber, and 7:5 parts sulphur -- was employed in each instance, but the amount of accelerator was varied according to the conditions of the experiment."
"All the accelerators soluble in alcohol were dissolved in the smallest quantity of this liquid and introduced into the rubber in solution. Those not soluble -- and this applied to the anhydroformaldehyde bodies only -- were
ground to 100 mesh and added to the rubber with the sulphur. After mixing, the mixtures were allowed a recovery period of 24 hrs. before they were vulcanized. Vulcanization was carried on in a platen press of the usual type."
TABLE 1 -- RELATIVE ACTIVITIES -- THIOUREA SERIES
Parts Required to Equal One Part Aniline
Aniline . . . . . . . . . . . . . . 1.000
Urea. . . . . . . . . . . . . . . . O.250
Thiourea. . . . . . . . . . . . . . O.300
Monophenylthiourea. . . . . . . . . O.450
Diphenylthiourea. . . . . . . . . . O.850
Monophenylguanidine (a) . . . . . . O.075
Diphenylguanidine (Sym.). . . . . . O.075
Triphenylguanidine. . . . . . . . . O.500
The activities of the various substances were compared in the mixture previously mentioned -- 92.5 parts of rubber and 7.5 parts of sulphur -- taking as a standard the effect obtained with one part of aniline, vulcanized for 90 min. at 148ˇ C. The amounts of various substances in the urea series required to effect the same degree of vulcanization as obtained with one part of aniline are shown in Table 1.
The paper thus shows that the activity and superiority of D.P.G. as an accelerator over T.P.G. is approximately as 7 is to 1.
In the answer to the bill in this case, the Kratz paper was set up as a defense, but, although read before September 6, 1919, it was not published until April, 1920.
Under § 4886, Revised Statutes, a person who claims to have invented any patentable improvement is not to be denied a patent because of any printed publication subsequent to his discovery, unless there was publication or public use or sale more than two years prior to his application. Kratz's article was not printed until less chanroblesvirtualawlibrary
than two years before Weiss' application for a patent in November, 1921, and therefore the paper could not be used as a basis for defense against his patent if his discovery was earlier than the publication. It nevertheless plays a very important part in understanding the facts in this case.
The main and only issue here is divided, by reason of the evidence and the lines of argument pursued, into two parts. The first is the effect of that part of it devoted to Weiss' discovery and his reduction to practice. The second is that part devoted to Kratz's discovery and his reduction to practice.
First. It is contended by the petitioner that the file wrapper and evidence show that the patent was secured by false evidence, and is not entitled to the presumption of validity which ordinarily accompanies the grant. The examiner in the Patent Office three times rejected the Weiss application, the third time by a reference to the Kratz paper. The hearing on that reference was ex parte. The third rejection was followed by acquiescence by the examiner because of two affidavits, one by Weiss and one by his fellow chemist, Daniels, who claimed to have been with him at the time in the laboratory of the Republic Rubber Company of Youngstown. In these final affidavits, Weiss had said that D.P.G. was produced and actually used "in the vulcanization of rubber goods" during the early part of the year 1919, and Daniels said:
"These tests were also carried out in the compounding laboratory for the various departments of the Republic Rubber Company at Youngstown, Ohio, and the accelerator proved to be highly efficient in the actual vulcanization of rubber goods, such as hose, tires, belts, valves and other mechanical goods."
It now appears without contradiction that the only rubber Weiss made during the early part of the year 1919 from D.P.G. was test slabs of rubber in which D.P.G. was the accelerator, and chanroblesvirtualawlibrary
that in fact neither he nor anybody in the rubber company had vulcanized rubber goods, as Daniels described them, before the Kratz publication. But we do not think this would invalidate the patent, for the reason that the actual fact was that these test slabs of rubber with D.P.G., if proven to be properly vulcanized, as the evidence seems to show, were a demonstration of the utility of D.P.G. as an accelerator and were a completed and demonstrated discovery constituting reduction to practice. Production of rubber goods for use or sale was not indispensable to the granting of the patent. Hence, the affidavits, though perhaps reckless, were not the basis for it, or essentially material to its issue. The reasonable presumption of validity furnished by the grant of the patent therefore would not seem to be destroyed.
Then it is claimed that the reference to the Kratz paper, which was not attacked by the applicant for its insufficiency as a reference under § 4886 of the Revised Statutes, should be treated as equivalent to a prior patent, the priority of which could only be overcome by evidence eliminating all reasonable doubt. The Barbed Wire Patent, 143 U. S. 275; Deering v. Winona Harvester Works, 155 U. S. 286, 155 U. S. 300; Clark Thread Co. v. Willimantic Linen Company, 140 U. S. 481, 140 U. S. 489. But the Kratz paper was not a prior patent, and, while it may be that other circumstances, such as a reference to a publication made before the application for the patent, may have the effect to require the same convincing proof of earlier discovery to avoid its effect (Westinghouse, etc. Co. v. Catskill, etc., Co., 121 F.8d 1, 834; New England Motor Co. v. Sturtevant Co., 150 F.1d 1, 137; Wendell v. American Laundry Machinery Co., 248 F.6d 8, 700), we do not think that the mere failure to invite the attention of the examiner to the defect of the reference under § 4886, Revised Statutes, calls for the strict rule of proof chanroblesvirtualawlibrary
to avoid the reference. This conclusion keeps the burden of proof on the defendant in attacking the patent on the ground of a prior use.
It is also claimed that, because the trial court in this cause found, after hearing the witnesses, the weight to be with the petitioner and against Weiss, assignor of respondent, his conclusions of fact, except for manifest error, are to be treated as unassailable. Adamson v. Gilliland, 242 U. S. 350, 242 U. S. 353; Davis v. Schwartz, 155 U. S. 631; Kimberly v. Arms, 129 U. S. 512; Tilghman v. Proctor, 125 U. S. 136, 125 U. S. 149, and Mason v. United States, 260 U. S. 545, 260 U. S. 556. We do not think that this rule applies in the case before, us at least to its full extent, first, for the reason that the circuit court of appeals, having considered all the evidence upon which the trial judge reached his conclusion, declined to approve of his findings, and second because, in the ,National Aniline & Chemical Co., case, which is in conflict with the case here, the trial judge reached a different conclusion on the same issue and the same evidence which we have here. Thomson Spot Welder Co. v. Ford Motor Co., 265 U. S. 445, 265 U. S. 447. We think therefore that the respondent is entitled under these conditions to retain a presumption of validity for his patent in the consideration of the case before us. This brings us then to the evidence which Weiss adduces in support of his first discovery of D.P.G. as an accelerator.
Morris L. Weiss received a degree in chemistry from the Cooper Union of New York City late in 1917, and attended a course of chemical study in the Polytechnic of Brooklyn. He entered the employ of the Republic Rubber Company of Youngstown, Ohio, in October, 1917. That company manufactured rubber articles largely from shoddy or reclaimed rubber. It was seeking to find an improved accelerator in T.P.G., and was building a plant chanroblesvirtualawlibrary
for its commercial use. Weiss, in addition to his usual work in T.P.G., became interested in 1918 and 1919 in the possibilities of the use of D.P.G. as an accelerator, which he had inquired into because it was mentioned with T.P.G. among the guanidines in a textbook of chemistry which he had read. He was required by the rules of the company to enter his experiments in a book called the "X Book," kept for the purpose. During the term of his employment, prior to September 6, 1919 (the date of Kratz's reading his paper), this X Book showed three dated and recorded experiments with D.P.G. as an accelerator. Two of these were with a shoddy mixture, and there is doubt whether they showed the marked superiority of D.P.G. over T.P.G., as Weiss in another case seems to have admitted. But there was another test with pure rubber recorded in the X Book of successful vulcanization by D.P.G., the date of which is in dispute. It was as follows:
Number X 2034
Made for accelerator tests --
Stretch 14 1/2
As it appears now, the date is February 10, 1919. Weiss does not deny that first figure of the date has been changed, but says that it was probably changed because it chanroblesvirtualawlibrary
was made originally by mistake as a "1," as on January 10, 1919, when it ought to have been as a "2," as in February, and the change was only to make it one month later. It is contended on the other side, and it was testified by an expert on handwriting, and the District Judge so held, that the change was made from 9-10-19 to 2-10-19, which would carry the original and correct date of this test to the later date of September 10, 1919, or three or four days later than the reading of the paper by Dr. Kratz to the American Chemical Society, and after Weiss had been informed by his colleague Daniels of Kratz's blackboard statement of the results of his discoveries. Weiss says he made other tests between the first successful one and the reading of the Kratz paper, but they are not recorded under specific dates, nor are they in regular order. There is a record of many tests after the Kratz paper, but none others are shown to be before it except by Weiss' and Daniels' unassisted memory.
Then it is said he did not claim discovery until his application for this patent in November, 1921, while, in an application for employment as a chemist at another rubber company in March, 1920, he did claim credit for the new process in commercially making D.P.G., but he attributed its importance to the revelation of the Kratz paper. His explanation is that he then supposed that accelerators were not patentable, and he was absorbed in cheapening the production of D.P.G.
Other circumstances are detailed at length in the brief of counsel to show that Weiss' real knowledge of the use of D.P.G. as an accelerator was prompted by Kratz's paper, and could not be independent discovery on his part before his hearing of and reading it. But, after full consideration of all the doubt-giving circumstances, we do not think that the attack on Weiss' proof of February 10, 1919, as the date when he first discovered by a completed chanroblesvirtualawlibrary
experiment the successful use of D.P.G. as an accelerator in making rubber, has overcome the evidence given to support it and the presumption of its correctness from the patent itself.
Second. Kratz's discovery. -- Dr. Kratz had been engaged in the chemistry of rubber and in its manufacture for more than seven years. He read his paper on D.P.G. and other accelerators in September, 1919. He had been employed as a chemist with the Diamond and Goodrich Companies, and, subsequently, with the Norwalk Tire & Rubber Company of Connecticut, for several years, and after April, 1917, with the Falls Rubber Company, of Cuyahoga Falls, near Akron, Ohio. He had directed his efforts to the subject of vulcanization almost exclusively, and was intimately familiar with the commercial practice therein. His first work with accelerators was as research chemist in 1913. On April 1, 1914, he went with the Norwalk Company in the capacity of chemist, and in April, 1917, he became chief chemist of the Falls Rubber Company.
In 1916, while with the Norwalk Company, Kratz prepared D.P.G. and demonstrated its utility as a rubber accelerator by making test slabs of vulcanized or cured rubber with its use. Every time that he produced such a slab, he recorded his test in cards which he left with the Norwalk Company and kept a duplicate of his own. By these tests, he arrived at figures representing the degree of superiority of D.P.G. over T.P.G. and other known accelerators, so that he could determine exactly how much D.P.G. it would be necessary to use to produce the same accelerating effect as would be produced by a larger amount of T.P.G. or of other accelerators in the same time. This work was known to, and was participated in, by his associate in the Norwalk Company, his immediate superior, and the chief chemist of the company, Dr. Russell, chanroblesvirtualawlibrary
who fully confirms Kratz's records and statement. This work was finally recorded in a carefully prepared contemporaneous report which Kratz left in the files of the Norwalk Company, and which is now produced by Dr. Russell in evidence before us. When Kratz left the Norwalk Company to go to the Falls Rubber Company, he took with him this record for his use in his future work, so that there are two records of the same thing. The report in 1916 was as follows:
"Relative Catalytic Effect of Compounds Related to Sulpho Carbaninide"
"The following formula was used to try out the activity of various substances more or less closely related to sulpho-carbaninide:"
White para . . . . . . . . . 100
Zinc oxide . . . . . . . . . 100
Sulphur. . . . . . . . . . . 5
"The following effects were recorded and, in cases where an acceleration was produced, the amounts required to give a cure in one hour equal to the cure produced by 3% of S-Carb, were as follows (in the first column):"
[As shown in
Paper, Sept., 1919
Aniline . . . . . . . . 3.50% 3.5
Di pheny this urea. . . 3.0% 2.975
Mono phenyl this urea . 1.5% 1.575
Thio urea . . . . . . . 1.0% 1.050
Tri phenyl guanidine. . 1.75% 1.750
Di phenyl guanidine . . O.25% O.262
Urea. . . . . . . . . . 0.33% O.875]
These results were confirmed by Kratz at the Falls Rubber Company in 1918 and 1919, and were reported chanroblesvirtualawlibrary
in his paper at the chemical meeting in September of 1919, as shown in the second column above, multiplied by 3.5 in order to put them on the same basis.
These values were determined by Kratz in some eight or nine tests in 1916 with each of the substances named, for which test slabs were made in each instance, and the series was extended until the desired result was obtained. The first substance is aniline, and the second is this (diphenylthiourea). These substances were generally known and widely used as accelerators, and therefore were used as standards of comparison. They show that Kratz's tests taught him in 1916 that D.P.G. was seven times as strong and as active as T.P.G. The report to the Norwalk Company also shows two different formulas by which Kratz made his own D.P.G. in 1916.
In the fall of 1917, when Kratz was chief chemist of the Falls Company, he received a special order for 1,000 inner tubes for automobile tires. In filling 300 tubes of this order of 1,000 tubes, which were made under Kratz's personal supervision -- for he had then become chief chemist of the Falls Company -- he used D.P.G. as an accelerator.
A little later, in 1918 and 1919, Kratz conducted at the Falls plant a series of tests with D.P.G. closely paralleling the series of tests which he had made in 1916 at the Norwalk plant and confirming those already reported as above. At Norwalk, he had used mostly zinc oxide as part of the rubber mix, and he desired to verify the results obtained in tests of the same accelerators in other compounds of rubber with other than zinc oxide. All this was part of the preparation of his paper on accelerators to be read before the 1919 meeting of the American Chemical Society. The year before, he had attended the 1918 meeting of the Society expecting to hear the subject discussed, but nothing was said, and so he and his assistant, chanroblesvirtualawlibrary
Flower, gathered their material for a paper at the next meeting. That paper, as read, covered much more than the mere demonstration of the utility of D.P.G. as an accelerator. It dealt with a number of other accelerators also. The authenticity and reliability of Dr. Kratz's testimony about them is not questioned in this record. It is not too much to say that the report of Dr. Kratz's results made a great impression upon the rubber chemists of the country.
The only lack of corroboration of Kratz, and the only challenge to his testimony of fact in this case, is in reference to his account of sending to a customer the 300 inner tubes for automobile tires accelerated by D.P.G. He says that they were sent to the purchaser, whose name he gives, and that they proved to be satisfactory, as he knew by having tagged them and having received approval of the whole lot by the purchaser. He says that this was a special order; that he had at the time a small supply of D.P.G. which he himself had made; that these 300 tubes exhausted his supply, and that, in filling the remainder, another accelerator was used. This sale and the use of D.P.G. as an accelerator took place in August, 1917, as shown by the memoranda that Kratz produces. The record of the shipment of the 1,000 tubes, the memorandum shipping order by Kratz and the O.K. by the president of the Falls Company, are introduced.
Kratz says he did not tell anyone of his use of D.P.G. in these 300 tubes. This is urged by respondent as a reason for discrediting it. Were this an isolated instance not taken out of the history of all of Kratz's relation to accelerators and to D.P.G., it might reasonably give rise to such question. But the undoubted fact that Kratz had demonstrated the utility of D.P.G. in his eight or nine tests in 1916 at Norwalk and the corporation of Dr. Russell as to his work there, and the memorandum which chanroblesvirtualawlibrary
he had taken with him of the tests and of the report to the Falls Rubber Company, and, indeed, the reflexive corroboration of his paper at Philadelphia, show undoubtedly that he knew the excellence of D.P.G. as an accelerator, and tend to confirm his account as to the 300-tube sale. It was not unnatural that, with a small amount of D.P.G., he should try it in a special order of this kind from which he might confirm the conclusion he had already reached. The effort to disprove it was vague and inconclusive, which, it is only fair to say, was to be expected five years after the event.
Kratz was not seeking a patent. He inferred, with reason, that D.P.G. would not make a successful business accelerator because of its then cost. He is wholly disinterested pecuniarily in the result of this case. The fact that he is the only witness is not fatal or any reason for denying its weight in connection with other circumstances. Reed v. Cutter, 1 Story 590, Fed.Cas. No. 11,645, 20 Fed.Cas. 435; Coffin v. Ogden, 18 Wall. 120; Egbert v. Lippmann, 104 U. S. 333.
But, even if we ignore this evidence of Kratz's actual use of D.P.G. in these rubber inner tubes which were sold, what he did at Norwalk, supported by the evidence of Dr. Russell, his chief, and by the indubitable records that are not challenged, leaves no doubt in our minds that he did discover in 1916 the strength of D.P.G. as an accelerator as compared with the then known accelerators, and that he then demonstrated it by a reduction of it to practice in production of cured or vulcanized rubber.
This constitutes priority in this case. It was not followed by commercial use thereafter because of the then cost of D.P.G. But this patent is for the mere discovery and application in the making of rubber of a particular accelerator. It was the fact that it would work with great activity as an accelerator that was the discovery, and chanroblesvirtualawlibrary
that was all, and the necessary reduction to use is shown by instances making clear that it did so work, and was a completed discovery. Bedford v. Hunt, 1 Mason, 302, Fed.Cas. No. 1217, 3 Fed.Cas. 37; Reed v. Cutter, supra; 51 U. S. Wilder, 10 How. 477; Coffin v. Ogden, supra.
It is said that these tests of Kratz were mere abandoned laboratory experiments. There was no abandonment in the sense that Kratz had given up what he was seeking for in demonstrating a new and effective accelerator in D.P.G. If he had been applying for a patent for the discovery, he clearly could have maintained proof of a reduction to practice. A process is reduced to practice when it is successfully performed. A machine is reduced to practice when it is assembled, adjusted, and used. A manufacture is reduced to practice when it is completely manufactured. A composition of matter is reduced to practice when it is completely composed. Walker on Patents, § 141a; Hunter v. Stikeman, 13 App.D.C. 214, 226; Mason v. Hepburn, 13 App.D.C. 86, 92; Lindemeyer v. Hoffman, 18 App.D.C. 1, 5; Roe v. Hanson, 19 App.D.C. 559, 564.
Nor were the tests of Kratz abandoned laboratory experiments. If so, then the cure by Weiss tested in February, 1919, was or the same character, and was not of itself a reduction to use. Weiss showed his production of vulcanized rubber with D.P.G. in February, 1919, only by a so-called laboratory experiment. He demonstrated the value of D.P.G. as an accelerator by exactly the same kind of experiment as that which Kratz had used two years before. Weiss founded his claim on the cured slab of rubber which had been vulcanized with D.P.G., and this Kratz had done two years earlier with slabs of the same kind and composition deposited in the same way in a platen mold. chanroblesvirtualawlibrary
Kratz's method of testing his rubber slabs is criticized. As already said, it is the method known as the thumb and tooth test. This is not so exact a method in determining all the qualities that a test machine would show in the product, but it is, as already said, one very generally used for practical purposes in factories in determining that the vulcanization or cure is complete. It was the one by the use of which Kratz disclosed and demonstrated to the rubber chemists of the country who listened to him in September, 1919. that D.P.G. was an accelerator, and how powerful it was as compared with others, and thereby revolutionized knowledge in the art, as the evidence abundantly shows and as Weiss himself asserted in his application for employment in 1920. It is true that, in the test by Weiss of February 10, 1919, the details of tensile strength and time of cure and elasticity were disclosed by machine test with more particularity, but the speed of the cure and the "activity" of D.P.G. and the fact of the cure were clearly shown by the simpler test.
It is a mistake to assume that reduction to use must necessarily be a commercial use. If Kratz discovered and completed, as we are convinced that he did, the first use of D.P.G. as an accelerator in making vulcanized. rubber, he does not lose his right to use this discovery when he chooses to do so for scientific purposes or purposes of publication, or because he does not subsequently sell the rubber thus vulcanized or use his discovery in trade, or does not apply for a patent for it. It is not an abandoned experiment because he confines his use of the rubber thus produced to his laboratory or to his lecture room. It is doubtless true that Kratz, by his course in respect to his discovery as to the use of D.P.G., has abandoned any claim as against the public for a patent, but that is a very different thing from saying that it chanroblesvirtualawlibrary
was abandoned as against a subsequent discoverer or patentee.
The conclusion we reach, then, is that, so far as this record shows, the first discovery that D.P.G. was a useful accelerator of the vulcanization of rubber was made by George Kratz, and not by Weiss.
We come then to the question of the validity of Claims 1, 5, and 9 of the patent, which seek to appropriate to the patentee the process of treating rubber by combining with the rubber compound "a disubstituted guanidine." Now the class of disubstituted guanidines includes not only D.P.G., but all other derivatives of guanidine in which two of the hydrogen atoms of guanidine nucleus have been substituted by other groups. The fact that disubstituted guanidines have been use as accelerators appeared in an article published by one Du Bosc, July 15, 1919, a fact which would defeat the claims applied for November 24, 1921. Moreover, the experts show that there are between 50 and 100 substances which answer this description, of which there is quite a number that are not accelerators at all. Weiss could certainly not claim the entire group of such compounds. He makes no showing that there is any general quality common to disubstituted guanidines which made them all effective as accelerators. Claims for their exclusive use cannot therefore be sustained. This is shown by the decision of this Court in this Incandescent Lamp Patent, 159 U. S. 465, where the Court said at page 159 U. S. 475:
"If, as before observed, there were some general quality, running through the whole fibrous and textile kingdom, which distinguished it from every other, and gave it a peculiar fitness for the particular purpose, the man who discovered such quality might justly be entitled to a patent; but that is not the case here."